MACKLANBURG-DUNCAN -- POLYCEL TRIPLE EXPANDING INSULATING FOAM 120Z/24OZ -- 8030-00F029220
===================== Product Identification ===================== Product ID:POLYCEL TRIPLE EXPANDING INSULATING FOAM 120Z/24OZ MSDS Date:02/11/1994 FSC:8030 NIIN:00F029220 === Responsible Party === Company Name:MACKLANBURG-DUNCAN Address:4041 NORTH SANTA FE Box:25188 City:OKLAHOMA CITY State:OK ZIP:73118-5000 Country:US Info Phone Num:405-528-4411 Emergency Phone Num:405-528-4411 CAGE:82464 === Contractor Identification === Company Name:MACKLANBURG-DUNCAN Address:4041 N SANTA FE Box:City:OKLAHOMA CITY State:OK ZIP:73118-0188 Country:US Phone:800-654-8454 / 405-528-4411 CAGE:82464 ============= Composition/Information on Ingredients ============= Ingred Name:HIGHER OLIGOMERS OF MDI, POLYMETHYLENE POLYPHENYLENE POLYISOCYANATE CAS:9016-87-9 RTECS #:TR0350000 Fraction by Wt: <23% Ingred Name:1,1'-METHYLENEBIS(ISOCYANATO-BENZENE), DIPHENYLMETHANE DIISOCYANATE *94-3* CAS:26447-40-5 Fraction by Wt: <23% Ingred Name:DIPHENYLMETHANEDIISOCYANATE (MDI), METHYLENE BIS (PHENYLISOCYANATE), 4,4 DIPHENYLMETHANE DIISOCYANATE (MDI) CAS:101-68-8 RTECS #:NQ9350000 Fraction by Wt: 17% Other REC Limits:0.005 PPM OSHA PEL:0.02 PPM ACGIH TLV:0.051 MG/CUM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CHLORODIFLUOROMETHANE, FREON 22, MONOCHLORODIFLUOROMETHANE CAS:75-45-6 RTECS #:PA6390000 Fraction by Wt: <30% Other REC Limits:1000 PPM OSHA PEL:1000 PPM ACGIH TLV:3540 MG/CUM Ozone Depleting Chemical:2 Ingred Name:ETHANE, 1-CHLORO-1,1-DIFLUORO-, CHLORODIFLUOROETHANE (DOT), FREON 142, DIFLUOROROMONOCHLOROETHANE CAS:75-68-3 RTECS #:KH7650000 Fraction by Wt: <30% Ozone Depleting Chemical:2 Ingred Name:PHOSPHORIC ACID, TRIS(2-CHLORO-1-METHYLETHYL) ESTER, TRICHLOROPROPYLPHOSPHATE CAS:13674-84-5 RTECS #:TC9000000 Fraction by Wt: 11% ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50(RAT) 15,000MG/KG (SEE SUPP) Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: NOSE & THROAT IRRITATION, REDUCED PULMONARY FUNCTION, DEATH. SKIN: IRRITATION. SENSITIZATION & DERMATITIS W/PROLONGED CONTACT. EYES: IRRITATION, REVERSIBLE CORNEAL DAMAGE, PHYSICAL DAMAGE. INGESTION: IRRITATION & CORROSIVE ACTION IN MOUTH & DIGESTIVE TRACT, OBSTRUCTION OF THE GI TRACT. Explanation of Carcinogenicity:NONE Effects of Overexposure:BREATHLESSNESS, SEVERE COUGHING, DYSPNEA, CHEST DISCOMFORT, IRRITATION, LIGHT HEADEDNESS, HEADACHE, GIDDINESS, SHORTNESS OF BREATH, NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS, DISCOLORATION, RE DDENING, SWELLING, BLISTERING Medical Cond Aggravated by Exposure:CHRONIC RESPIRATORY PROBLEMS, ISOCYANATE SENSITIZATION ======================= First Aid Measures ======================= First Aid:INHALATION: TREAT SYMPTOMATICALLY W/VASO-DILATORS & OXYGEN. SKIN: PRODUCT ADHERES TO SKIN LIKE AN ADHESIVE. WASH IMMEDIATELY W/ABRASIVE SOAP, ACETONE/ALCOHOL & A STIFF VEGETABLE BRUSH. AFTER PRODUCT C URES IT CAN ONLY BE REMOVED MECHANICALLY. EYES: FLUSH W/WATER FOR 15 MINS. INGESTION: UNCURED FOAM MAY CURE W/IN THE GI TRACT. DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES. ===================== Fire Fighting Measures ===================== Extinguishing Media:CO2, FOAM, DRY CHEMICAL, HIGH EXPANSION CHEMICAL FOAM Fire Fighting Procedures:WEAR POSITIVE PRESSURE SCBA & FULL PROTECTIVE GEAR. COOL FIRE EXPOSED CONTAINERS W/COLD WATER. Unusual Fire/Explosion Hazard:IRRITATING/TOXIC GASES MAY BE PRODUCED DURING BURNING. SEALED CONTAINERS CONTAIN FREON WHICH MAY EXPAND UNDER PRESSURE & EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR IMPERVIOUS GLOVES, SAFETY GLASES & APPROPRIATE WORK CLOTHES. COVER W/ABSORBENT MATERIAL SUCH AS SAWDUST. PLACE IN OPEN TOP CONTAINERS/PLASTIC SHEET. AFTER CURING, MATERIAL CAN ONLY BE REMOVED MEC HANICALLY. ====================== Handling and Storage ====================== Handling and Storage Precautions:DON'T STORE NEAR HEAT SOURCES, SPARKS/FLAME. STORE BETWEEN 40F & 120F. DON'T FREEZE. KEEP OUT OF REACH OF CHILDREN. DON'T INGEST. Other Precautions:DON'T STORE IN CARS, CAR TRUNKS, OUTSIDE IN DIRECT SUNLIGHT ON HOT DAYS/IN ANY LOCATION WHERE TEMP MAY EXCEED 120F. IF CAN IS STORED AT TEMPS <40F, CONTENTS MAY SEPARATE. SHAKE CAN VIGOROUSLY TO RECOM BINE. AVOID CONTACT W/SKIN & INHALATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:AIR PURIFYING/POSITIVE PRESSURE SUPPLIED AIR SYSTEM/SCBA. Ventilation:MECHANICAL EXHAUST ADEQUATE TO MAINTAIN BELOW TLV Protective Gloves:CHEMICALLY RESISTANT RUBBER/PLASTIC Eye Protection:SAFETY GOGGLES/FACE SHIELD Work Hygienic Practices:WASH SKIN & HANDS AFTER USE. REMOVE & LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health USE ONLY IN WELL-VENTILATED AREA. VAPORS OF POLYCEL MAY CONTAIN TRACE LEVELS OF FREE ISOCYANATES & PROPELLANT. USE ENTIRE CAN OF FOAM W/IN 30 DAYS OF INITIAL APPLICATION. BOILING POINT, VAPOR PRESSURE & EVAPORATION RATE ARE FOR HYDROCHLOROFLUOROCARBON PROPELLANT. ORAL LD50 INFORMATION IF FOR POLYMERIC DIISOCYANATE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:-19F (SUPP) Vapor Pres:79.4(SUPP) Vapor Density:3.25 Spec Gravity:1.08 Evaporation Rate & Reference:(BU AC=1): >1 (SEE SUPP) Solubility in Water:INSOLUBLE Appearance and Odor:CREAM COLORED, VISCOUS FOAM W/SLIGHT SWEET ODOR. SOLID UPON CURING. Percent Volatiles by Volume:30 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, STRONG CAUSTICS, AMINES, SOME METAL COMPOUNDS ALCOHOLS Stability Condition to Avoid:WATER CONTAMINATION, FREEZING, HEAT Hazardous Decomposition Products:CO2, CO, NITROUS OXIDES, HYDROGEN CYANIDE, ISOCYANURATES, METHYLENE BIS(PHENYLISOCYANATE) VAPORS, FLUOROCARBON VAPORS ==================== Disposal Considerations ==================== Waste Disposal Methods:IF EXCESS PRODUCT, VENT CAN & FOAM INTO A SUITABLE WASTE CONTAINER. ALLOW TO CURE & DISPOSE OF IN A SANITARY LANDFILL IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE/PUNCTURE CAN. EMPTY CAN COMPLETELY BEFORE DISPOSAL. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.