BARTLETT CHEMICALS -- BATTERY FLUID,SULFURIC ACID CLASS II -- 6810-01-031-4652
===================== Product Identification ===================== Product ID:BATTERY FLUID,SULFURIC ACID CLASS II MSDS Date:12/17/1993 FSC:6810 NIIN:01-031-4652 === Responsible Party === Company Name:BARTLETT CHEMICALS Address:4955 RIVER ROAD City:JEFFERSON State:LA ZIP:70121 Country:US Info Phone Num:504-734-1971 Emergency Phone Num:504-734-1971 CAGE:1V771 === Contractor Identification === Company Name:BARTLETT CHEMICALS Address:4955 RIVER ROAD Box:10710 City:JEFFERSON State:LA ZIP:70121 Country:US Phone:504-734-1971 CAGE:1V771 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA) CAS:7664-93-9 RTECS #:WS5600000 Fraction by Wt: 49 - 51% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3/3 STEL; 9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE Other REC Limits:NONE RECOMMENDED OSHA PEL:NOT RELEVANT ACGIH TLV:NOT RELEVANT ===================== Hazards Identification ===================== LD50 LC50 Mixture:RAT,LC50:510MG/M3/2H;LD50:2140MG/KGRTECS Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS. ACUTE- CORROSIVE! CAUSES SEVERE EYES & SKIN BURNS. MIST IS EXTREMELY IRRITATING TO RESPIRATORY TRACT. CONTACT WITH EYES MAY RESULT IN BLINDNESS. SWALL OWING MAY BE FATAL. INHALATION MAY DAMAGE RESPIRATORY TRACT. CHRONIC- MAY CAUSE DENTAL EROSION, DERMATITIS, BRONCHITIS. Explanation of Carcinogenicity:NONE Effects of Overexposure:SEVERE IRRITATION AND BURNING, VISUAL IMPAIRMENT, DENTAL EROSION, COUGH, POSSIBLE CHARRING OF SKIN, PAIN, BLINDNESS Medical Cond Aggravated by Exposure:OPEN WOUNDS AND SORES, RESPIRATORY AILMENTS SUCH AS EMPHYSEMIA AND BRONCHITIS ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION IMMEDIATELY. EYE/SKIN:IMMEDIATELY FLUSH WITH WATER FOR 15-20 MINUTES. HOLD EYELIDS OPEN. CONTINUE RINSING WITH NORMAL SALINE UNTIL PH=7. INHALED:REMOVE TO FRESH AIR. PROVIDE OXYG EN/CPR IF NEEDED. ORAL:DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK LARGE AMOUNT OF WATER/MILK. INGESTED ACID MUST BE DILUTED ABOUT 100 FOLDS. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, SAND, FOAM/DRY CHEMICAL. COOL FIRE EXPOSED CONTAINERS WITH WATER. NO WATER OVER ACID. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:VIOLENT REACTION WITH WATER. EVOLUTION OF EXPLOSIVE HYDROGEN GAS ON CONTACT WITH MOST METALS. WILL REACT WITH ORGANIC MATERIAL YIELDING HEAT & DENSE WHITE FUMES ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. REMOVE IGNITION SOURCES(H2 MAY BE PRESENT). KEEP COMBUSTIBLES AWAY. STOP LEAK IF POSSIBLE. VENTILATE & NEUTRALIZE WITH SODA ASH/LIME. ABSORB WITH INERT MATERIAL. SCOOP INTO DRUM. DO NOT GET WATER INSIDE CONTAINER/SPILL. Neutralizing Agent:SUITABLE ALKALI SUCH AS LIME OR SODA ASH ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINER, AWAY FROM INCOMPATIBLE MATERIALS. KEEP OUT OF REACH OF CHILDREN. Other Precautions:WHEN DILUTING, SLOWLY ADD ACID TO WATER WHILE STIRRING, TO AVOID SPATTERING, BOILING AND ERUPTION. DO NOT STRIKE CONTAINERS OR FITTINGS WITH TOOLS. STORE AWAY FROM SOURCES OF IGNITION. EMPTIED CONTAIN ER WILL RETAIN PRODUCT RESIDUE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED, FULL-FACED RESPIRATOR WITH CANISTER APPROVED FOR SULFURIC ACID VAPOR & MIST IF TLV EXCEEDED. IF CONCENTRATIONS ARE HIGH/UNKNOWN, USE SELF-CONTAINED BREATHING APPARATUS. Ventilation:PROVIDE VENTILATION TO CONTROL EXPOSURE LEVELS BELOW AIRBORNE EXPOSURE LIMITS. USE LOCAL EXHAUST VENTILATION. Protective Gloves:RUBBER Eye Protection:SPLASH-PROOF CHEMICAL SAFETY GOGGLES Other Protective Equipment:PROTECTIVE CLOTHING, RUBBER FOOTWEAR, ACID RESISTANT HOOD AND FULL BODY SUIT RECOMMENDED, SAFETY SHOWER, EYEWASH. Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:C1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:B.P. Text:640F,338C Vapor Pres:VARIABLE Spec Gravity:1.3945 - 1.4042 pH:1.0 Solubility in Water:SOLUBLE Appearance and Odor:CLEAR LIQUID - PRACTICALLY ODORLESS ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACETALDEHYDE, ALCOHOLS, STRONG BASES, CHLORATES, NITRATES, CARBIDES, MOST METALS, ORGANIC MATERIALS, WATER, PICRATES Stability Condition to Avoid:ADDING WATER TO ACID (ALWAYS ADD ACID SLOWLY TO WATER) Hazardous Decomposition Products:TOXIC OXIDES OF SULFUR ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF SPILLED, NEUTRALIZED, OR WASTE PRODUCT, CONTAMINATED SOIL, AND OTHER MATERIALS IN ACCORDANCE WITH ALL LOCAL, STATE, AND FEDERAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER D002. REPORTABLE QUAN TITY (RQ): 1000 LBS. DO NOT FLUSH ACID TO SEWER. 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