CENEX/LAND O LAKES AG SERVICES -- REGULAR UNLEADED AUTOMOTIVE GASOLINE -- 9130-01-055-0816
===================== Product Identification ===================== Product ID:REGULAR UNLEADED AUTOMOTIVE GASOLINE MSDS Date:02/01/1990 FSC:9130 NIIN:01-055-0816 === Responsible Party === Company Name:CENEX/LAND O LAKES AG SERVICES Address:NW 9087 Box:1450 City:MINNEAPOLIS State:MN ZIP:55485-9087 Country:US Info Phone Num:612-451-5151 Emergency Phone Num:612-451-5151/800-424-9300(CHEMTREC) CAGE:KO281 === Contractor Identification === Company Name:CENEX/LAND O LAKES AG SERVICES Address:NW 9087 Box:1450 City:MINNEAPOLIS State:MN ZIP:55485-9087 Country:US Phone:612-451-5151 CAGE:KO281 Company Name:CENEX/LAND O'LAKES AG SERVICES Box:64089 City:ST PAUL State:MN ZIP:55164-0089 Country:US Phone:612-451-5151 CAGE:0LMC0 ============= Composition/Information on Ingredients ============= Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III) CAS:95-63-6 RTECS #:DC3325000 Fraction by Wt: < 12% Other REC Limits:NONE SPECIFIED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9192 Ingred Name:HYDROCARBONS (AROMATIC & PARAFFINIC) Fraction by Wt: 50-80% % Other REC Limits:NONE SPECIFIED Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: < 5% Other REC Limits:NONE SPECIFIED OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:ETHYL BENZENE (SARA III) CAS:100-41-4 RTECS #:DA0700000 Fraction by Wt: 1 - 3% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/125 STEL ACGIH TLV:100 PPM/125STEL 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CYCLOHEXANE (SARA III) CAS:110-82-7 RTECS #:GU6300000 Fraction by Wt: < 2% Other REC Limits:NONE SPECIFIED OSHA PEL:300 PPM ACGIH TLV:300 PPM, 9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:CUMENE (SARA III) CAS:98-82-8 RTECS #:GR8575000 Fraction by Wt: < 2% Other REC Limits:NONE SPECIFIED OSHA PEL:S, 50 PPM ACGIH TLV:S, 50 PPM; 9192 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 10-15% Other REC Limits:NONE SPECIFIED OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 10-20% % Other REC Limits:NONE SPECIFIED OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:METHYL TERT-BUTYL ETHER (SARA III) CAS:1634-04-4 RTECS #:KN5250000 Fraction by Wt: < 15% Other REC Limits:NONE SPECIFIED EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES Health Hazards Acute and Chronic:INHALATION CAUSES INTENSE BURNING OF MUCOUS MEMBRANES, THROAT AND RESPIRATORY TRACT, BRONCHOPNEUMONIA, PULMONAY EDEMA. REPEATED OR PROLONGED SKIN CONTACT CAUSES DERMATITIS, BLISTERING OF THE SKIN, DEF ATTING. EYE CONTACT MAY CAUSE HYPEREMIAOF THE CONJUNCTIVA. INGESTION MAY CAUSE CENTRAL NERVOUS SYSTEM DISTURBANCES. Explanation of Carcinogenicity:THIS PRODUCT CONTAINS BENZENE WHICH IS LISTED AS A CARCINOGEN BY NTP, IARC AND OSHA. Effects of Overexposure:BURNING OF MUCOUS MEMBRANES, THROAT, RESPIRATORY TRACT, BRONCHOPNEUMONIA, PULMONAY EDEMA, DERMATITIS, SKIN BLISTERING, DEFATTING, INEBRIATION, DROWSINESS, BLURRED VISION, VERTIGO, CONFUSION, VOMITING, UNCONSCIOUSNESS, CONVULSIONS, CYANOSIS. ASPIRATION HAZARD. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN CONDITIONS MAY BE AGGRAVATED BY EXPOSURE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES INCLUDING UNDER EYELIDS. CALL A PHYSICIAN. SKIN: REMOVE CONTAMINATED CLOTHING. WASH EFFECTED AREA WITH SOAP AND WATER. IF IRRITATION DEVELOPS, CALL A P HYSICIAN. INHALTION: REMOVE TO FRESH AIR. RESSTORE BREATHING AND ADMINISTER OXYGEN IF NEEDED. INGESTION: DO NOT INDUCE VOMITING! CONTACT A PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-50F,-46C Lower Limits:1.4 % Upper Limits:7.6 % Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM Fire Fighting Procedures:USE OF WATER MAY BE INEFFECTIVE TO EXTINGUISH FIRE, BUT USE WATER SPRAY TO COOL FIRE EXPOSED DRUMS AND TANKS. FIRE-FIGHTERS SHOULD WEAR SCBA AND PROTECTIVE GEAR Unusual Fire/Explosion Hazard:VAPORS CAN FLOW ALONG SURFACES, REACH DISTANT IGNITION SOURCES AND FLASH BACK. CAN REACT VIOLENTLY WITH OXIDIZING AGENTS. ================== Accidental Release Measures ================== Spill Release Procedures:REPORT SPILLS AS REQUIRED. REMOVE SOURCES OF HEAT OR IGNITION. PROVIDE ADEQUATE VENTILATION. CLEAN-UP PERSONNEL REQUIRE PROTECTION AGAINST LIQUID CONTACT AND VAPOR INHALATION. CONTAIN SPILL. DO NOT AL LOW TO ENTER SEWER OR SURFACE WATER. ADD ABSORBENT Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN CLOSED CONTAINERS IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM SOURCES OF HEAAT, IGNITION AND STRONG OXIDIZING AGENTS. Other Precautions:PROTECT CONTAINERS FROM PHYSICAL DAMAGE. AVOID DIRECT SUNLIGHT. OUTDOOR OR DETACHED STORAGE PREFERRED. NO SMOKING IN AREAS OF USE. PREVENT STATIC ELECTRIC SPARKS AND USE EXPLOSION-PROOF ELECTRICAL SER VICES. AVOID SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROPRIATE NIOSH RESPIRATOR SHOULD BE AVIALABLE FOR NON-ROUTINE OR EMERGENCY USE ABOVE THE TLV. Ventilation:USE GENERAL AND LOCAL EXHAUST VENTILATION (EXPLOSION-PROOF) TO KEEP VAPORS BELOW THE TLV REQUIREMENTS IN THE WORKPLACE. Protective Gloves:RUBBER GLOVES Eye Protection:CHEMICAL SAAFETY GOGGLES OR FACESHIELD Other Protective Equipment:RUBBER BOOTS, CLOTHING TO BE CHANGED DAILY AND LAUNDERED. EYEWASH FOUNTAINS, SHOWERS AND WASHING FACILITIES. Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND BEFORE EATING DRINKING OR SMOKING. Supplemental Safety and Health PROVIDE SUITABLE TRAINING TO THOSE HANDLING AND WORKING WITH THIS MATERIAL. AVOID INHALATION OF VAPORS. INDOOR USE OF THIS MATERIAL REQUIRES EXHAUST VENTILATION TO REMOVE VAPORS. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:80.0F,26.7C Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN Vapor Pres:275-475 Vapor Density:3.0 - 4.0 Spec Gravity:0.65-0.75 Evaporation Rate & Reference:NOT GIVEN Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, MOBILE LIQUID WITH A CHARACTERISTIC GASOLINE ODOR Percent Volatiles by Volume:100 % ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZERS Stability Condition to Avoid:SPARKS, IGNITION SOURCES, OPEN FLAMES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, HYDROCARBONS ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN SCRAP MATERIAL IN AN APPROVED INCINERATOR. BURN CONTAMINATED IQUID BY SPRAYING INTO AN INCINERATOR. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.